The structure of 1D CuI crystals inside SWNTs.

Kiselev NA, Zakalyukin RM, Zhigalina OM, Grobert N, Kumskov AS, Grigoriev YV, Chernysheva MV, Eliseev AA, Krestinin AV, Tretyakov YD, Freitag B, Hutchison JL

Nanocomposites consisting of one-dimensional CuI crystals inside single-walled carbon nanotubes were obtained using the capillary technique. high-resolution transmission electron microscopy investigations of the atomic structure of the encapsulated 1D CuI crystals revealed two types of 1D CuI crystals with growth direction and relative to the bulk hexagonal CuI structure. Atomic structure models were proposed based on the high-resolution transmission electron microscopy images. According to the proposed models and image simulations, the main contrast in the 1D crystal images arises from the iodine atoms whereas copper atoms, with lower atomic number giving lower contrast, are thought to be statistically distributed.