Publication News

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Model of N@C60 with addend

5th December 2017

Synthesis and EPR studies of the first water-soluble N@C60 derivative

Researchers from the Carbon Nanomaterials Group under Professor Kyriakos Porfyrakis have recently published a report in Chemical Communications showing synthesis of the first water-soluble derivative of the paramagnetic endohedral fullerene N@C60,  through the covalent attachment of a single addend containing two permethylated β-cyclodextrin units to the surface of the carbon cage. The capability of the derivative to function as a spin probe for Cu(II) ions is demonstrated in competitive organic solvents using X-band EPR. This research opens the door for medical applications for this endohedral fullerene such as a potential spin probe.  This article was featured on the cover of the journal.

28th November 2017

Keeping Perfect Time With Caged Atoms

Prof Kyriakos Porfyrakis and Dr Edward Laird have published in IEEE Spectrum a feature article about their work on building the world's smallest atomic clock, based on a Nitrogen atom trapped in an endohedral fullerene C60 molecule. They have patented the technology which is being commercially developed under spinout company Designer Carbon Materials. The aim is to one day incorporate a complete atomic clock into one chip, avoiding the need for optical elements used in conventional atomic clocks. An endofullerene-based atomic clock could thus be small, light, and energy efficient. Potentially, it could replace many of the quartz oscillators used in nearly every present-day electronic device to keep time.

17th November 2017

Calculating with light using a chip-scale all-optical abacus

Machines that simultaneously process and store multistate data at one and the same location can provide a new class of fast, powerful and efficient general-purpose computers. An article in Nature Communications  by researchers in the Advanced Nanoscale Engineering Group demonstrates the central element of an all-optical calculator, a photonic abacus, which provides multistate compute-and-store operation by integrating functional phase-change materials with nanophotonic chips. 


20th October 2017

Modelling of a vacuum metallization patterning method for organic electronics

The high throughput roll-to-roll patterning of metal thin films could be used to create organic functional devices. Researchers in the Polymers Group have reported in Surface and Coatings Technology research into the compatibility of an in-vacuum selective metallization technique, which uses a sacrificial oil to define the metal electrode pattern for functional devices.  The metal thin film properties were found to be very attractive, compared to solvent based equivalents. The sheet resistance and roughness, 1.59 Ω·sq−1 and 3.24 × 10− 8 m2 respectively, particularly set this high-throughput process apart as a promising technique for creating cost effective flexible electronics and organic devices.

Small Cover Article

16th October 2017

A Nanophotonic Structure Containing Living Photosynthetic Bacteria

In experiments depicted on the front cover of the new issue of Small, members of the Photonic Nanomaterials Group in collaboration with researchers at Sheffield, Harvard and Clark Universities have demonstrated the strong coupling of living photosynthetic bacteria to optical microcavities. This coupling causes excitons in the bacteria and photons of light in the cavity to hybridize into quasi-particles known as polaritons, adopting properties of both particle type and changing the energy level structure compared with the uncoupled systems. By controlling the separation of the mirrors that form the cavity, the polariton energies and properties can be tuned. The experiments open prospects for engineering optical devices that involve living organisms or for modifying life processes by optical coupling.

Molecular Heat Engines


6th October 2017

Molecular heat engines

Conventional heat engines convert a temperature difference into mechanical work. Similarly, molecular heat engines use quantum transport to turn a thermal energy into electrical power. Molecular heat engines are small and do not have any moving parts, therefore they are ideal for low-power applications. Researchers in the Quantum Electronic Devices Group report in Nano Letters on the measurement of the thermoelectric power conversion of individual C60 molecules in a graphene nanogap. They achieve energy conversion rates close to the theoretical limit by carefully engineering the molecular energy levels, providing a viable pathway towards on-chip cooling and energy harvesting for quantum technologies.

Photonic Synapse

6th October 2017

On-chip photonic synapse

The search for new “neuromorphic computing” architectures that mimic the brain’s approach to simultaneous processing and storage of information is intense. Because, in real brains, neuronal synapses outnumber neurons by many orders of magnitude, the realization of hardware devices mimicking the functionality of a synapse is a first and essential step in such a search. Researchers in the Advanced Nanoscale Engineering Group report  in Science Advances  the development of such a hardware synapse, implemented entirely in the optical domain via a photonic integrated-circuit approach. Using purely optical means brings the benefits of ultrafast operation speed, virtually unlimited bandwidth, and no electrical interconnect power losses. Also see MPLS news article.

Phase Change RAM

14th September 2017

Materials science and engineering of phase change random access memory

With scaling-limit of current silicon technology becoming very apparent, there is growing search for alternate data computation and storage systems. Phase Change Materials based Phase Change Memory (PCRAM) is amongst the most promising candidate. In a review article published in Materials Science and Technology by Syed Ghazi Sarwat from Advanced Nanoscale Engineering Group, this technology is detailed from rudiments, covering essentials topics and advances. This review is also the winner of 2017 Literature Review Prize by IOM3 and Taylor and Francis.

EHD printing nanoparticles

14th September 2017

Nanoparticle assembly enabled by EHD-printed monolayers

Researchers in the Advanced Nanoscale Engineering Group have published in Nature Microsystems & Nanoengineering research combining self-assembly and printing to achieve additively nanomanufactured structures. They showed that monolayers can drive the assembly of nanoparticles into pre-defined patterns with single-particle resolution; then crucially demonstrated for the first time that molecular monolayers can be printed using electrohydrodynamic (EHD)-jet printing. The functionality and resolution of such printed monolayers drives the self-assembly of nanoparticles, demonstrating the integration of EHD with self-assembly. This shows that such process combinations can lead towards more integrated process flows in nanomanufacturing. This article was highlighted as the feature article for the journal issue.


11th September 2017

New software for atomic pair distribution function (PDF) analysis of amorphous and polycrystalline materials

Janaki Shanmugam, Konstantin Borisenko and co-authors in Electron Image Analysis Group have released eRDF Analyser software, a new free and open code software that brings to the masses computation of atomistic pair distribution function (PDF) from electron diffraction data. An easy to use and interactive interface of the software allows straightforward calculation of the PDF that represents distribution of interatomic distances in amorphous and polycrystalline materials. Analysis of such materials is often required in various applications, from energy materials to catalyst nanoparticles. The software is described in SoftwareX publication.

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